Helena Vasconcelos

By Cristina Vasconcelos

Part of the book: Sintering of Ceramics

By Helena Cristina Vasconcelos and Afonso Silva Pinto

Glasses may be prepared by sol-gel processing over a wide range of compositions and thick multilayer deposits may be used as waveguides for integrated optics. Doping these layers with rare-earth (RE) ions enables the fabrication of active devices for optical amplifiers; the incorporation of these ions into nanocrystallites offers possibilities for increased dopant concentration without fluorescence quenching, improved spectroscopic performance and high quantum yields. Rare-earth (RE) ions such as erbium (Er3+), ytterbium (Yb3+), neodymium (Nd3+), thulium (Tm3+), holmium (Ho3+) and praseodymium (Pr3+) have been widely used in optical applications and cover a range of wavelengths ranging from UV-visible to the near infrared. This chapter includes basic principles of fluorescence in RE doped glasses, fluorescence lifetimes, quantum yields and Judd-Ofelt analysis. A few information is given about the preparation and characterization of glasses, thin films and glass-ceramics (nanocrystallites embedded in glass matrix) prepared by sol-gel processing. The growth of nanocrystals in glassy sol-gel films through suitable heat treatments can avoid the influence of high phonon energy of silica glasses. The characterization of such materials can be evaluated by optical techniques, namely UV-Visible, FTIR, among other additional techniques that include Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD) and Atomic Force Microscopy (AFM).

Part of the book: Recent Applications in Sol-Gel Synthesis

By Helena Cristina Vasconcelos

This chapter focuses on developing coatings for use as waveguides for integrated optics and photonics. Thin (or thick) films of silica-based inorganic materials and organic-inorganic hybrids can be easily obtained using the sol-gel and spin-coating method, followed by rapid thermal annealing to obtain dense films of good optical quality. The waveguide thermal, structural, and optical properties can be characterized using differential thermal analysis, X-ray diffraction, Fourier-transform infrared spectroscopy, Raman spectroscopy, scanning electron microscopy, and atomic force microscopy. Waveguides can be both doped with semiconductor microcrystallites and rare-earths for the development of optical devices, where light is confined to one or two dimensions (planar, channel or strip loaded).

Part of the book: Electromagnetic Propagation and Waveguides in Photonics and Microwave Engineering

By Helena C. Vasconcelos, Joao A. Lopes, Maria João Pereira and Afonso Silva Pinto

Many aquatic ecosystems, such as lagoons or lakes, are increasingly vulnerable to climate changes and human pressure. The environmental and economic costs of anthropogenic eutrophication are high as well as the applied methods to counteract eutrophication This chapter analyzes the variation in abundance (and biomass) of several phytoplankton families in one of the most well-known volcanic lagoons in the Archipelago of the Azores-Portugal (Furnas Lagoon) and the dynamic correlation between groups of different types of algae that have been established seasonally between 2003 and 2018. For that purpose, the principal component analysis (PCA) technique was used in data series on biomass and abundance of phytoplankton and chlorophyll a, in the time interval considered. The application of PCA techniques in natural phytoplankton populations offers the possibility of making rapid qualitative diagnoses of the trophic state in natural lakes. On the other hand, the fluorescence properties of phytoplankton microorganisms are strongly affected by the physicochemical properties of natural waters. The fluorescence emission and the lifetime of the different water samples were obtained by photon counting with time correlation (TCSPC), allowing to establish the fluorescent signature of these phytoplankton groups under certain conditions.

Part of the book: Fluorescence Methods for Investigation of Living Cells and Microorganisms

By Helena Cristina Vasconcelos

The field of photonics has been the target of constant innovations based on a deep knowledge of the nonlinear optical (NLO) properties of materials and especially on information/data technologies. This chapter compiles some of the main physical aspects needed to understand NLO responses, especially in glasses. Any deviation from the linear correlation between a material’s polarization response and the electric component of an applied electromagnetic field is an example of nonlinear optic behavior. Heavy metal oxide and chalcogenide glasses offer the largest nonlinear response. For example, high refractive index and high dispersion glasses fall in the type of non-resonant devices, while the resonant ones comprise metal nanoparticle doped glasses. Metal nanoparticles’ doped glasses can be pre- pared by the sol-gel method. The optical absorption spectrum of Ag-doped silica glass shows the presence of an absorption band of surface Plasmon Resonance due to Ag nanoparticles at 420 nm and Z-scan has been used to study the NLO properties. This chapter contains a brief discussion of the basic principles of nonlinear optics, the review of the nonlinear optical of glass in general, and two separate sections concerning the nonlinear optical effects in the glasses doped with quantum dots and metals, respectively.

Part of the book: Nonlinear Optics

By Helena Cristina Vasconcelos, Telmo Eleutério, Maria Gabriela Meirelles and Susana Sério

The surface functionalization of natural fibers, mainly using TiO2 films, shows a growing interest in its application as yarns in fabrics that require advanced properties, allowing the use of their excellent physical and chemical properties in the textile area. The DC magnetron sputtering technique is a potential method for depositing TiO2 films onto natural fibers, allowing for the creation of advanced and competitive properties compared to synthetic fibers. Different crystalline phases of TiO2 have been shown to be effective in photocatalytic applications. Reactive discharges like the Ar/O2 gas mixture can be used to deposit TiO2 films with desired characteristics, and controlling deposition parameters can further manipulate the properties of the coatings. Analytical techniques such as XRD, XPS, and SEM/EDS can be used to study the surface properties of TiO2 films. XRD determines crystal structure, XPS provides information on chemical composition, and SEM/EDS examines morphology and elemental composition.

Part of the book: Updates on Titanium Dioxide

By Helena Cristina Vasconcelos

This chapter provides a comprehensive exploration of optical fluorescence intensity ratio (FIR) temperature sensing, blending theoretical underpinnings with practical applications. It underscores the intrinsic sensitivity and non-invasiveness of FIR technology, spanning diverse scientific disciplines where its utility is paramount. Central to the discussion are the intricate energy transfer mechanisms within fluorescence emissions from temperature-sensitive materials, revealing their nuanced responses to thermal changes. Fundamental to FIR thermometry are the lanthanide (Ln³⁺) ions, which play pivotal roles due to their unique electronic configurations. These elements exhibit temperature-dependent variations in fluorescence properties, including intensity and lifetime, crucial for accurate temperature determination. Specifically, the chapter delves into the utilization of erbium (Er³⁺) and holmium (Ho³⁺) ions in the context of FIR thermometry, highlighting their distinct contributions to enhancing temperature sensitivity. The Er³⁺/Ho³⁺ co-doped nano-garnet emerges as a promising material in this field, effectively bridging theoretical frameworks with practical implementations. The narrative is enriched by the incorporation of the Boltzmann distribution equation, which provides a robust theoretical foundation for understanding temperature-dependent fluorescence phenomena exhibited by Ln³⁺ ions. This chapter serves as a valuable resource, offering a concise understanding on the forefront of optical FIR-based thermometry for researchers and professionals alike.

Part of the book: Luminescence - Emerging New Applications [Working title]