Increasing the volumetric energy density of redox flow batteries beyond that of the archetypal all-vanadium system requires the development of highly soluble charge carriers that can store multiple electrons per charge cycle. In this review article we will describe the design and performance of a range of new charge carriers for flow batteries, with an emphasis on those with multi-electron redox properties. These include fullerene derivatives, multifunctional organic systems, metal coordination complexes, and polyoxometalates. Our discussion will include an evaluation of the fundamental physical and electrochemical properties of the charge carriers and their impact on battery performance and energy density.
Part of the book: Redox Chemistry